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selectivity factor definition

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A quantitative representation of selectivity in aromatic substitution reactions (usually electrophilic, for monosubstituted benzene derivatives). If the partial rate factor, f, expresses the reactivity of a specified position in the aromatic compound PhX relative to that of a single position in benzene, then the selectivity factor Sf (expressing discrimination between p- and m-positions in PhX) is defined as

Sf = lg (fpX/fmX).STOCK and BROWN (1963).


See also:

Separatory funnel definition
Sequence definition
sesquiterpenoids definition
sigma bonds definition
set point definition