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multi-centre bond definition

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Representation of some molecular entities solely by localized two-electron two-centre bonds appears to be unsatisfactory. Instead, multi-centre bonds have to be considered in which electron pairs occupy orbitals encompassing three or more atomic centres. Examples include the three-centre bonds in diborane, the delocalized pi bonding of benzene, and bridged carbocations.

See also:

NADPH definition
multiplexing definition
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