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inner-sphere (electron transfer) definition
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Historically an electron transfer between two metal centres sharing a ligand or atom in their respective coordination shells. The definition has more recently been extended to any situation in which the interaction between the donor and acceptor centres in the transition state is significant (>20 kJ mol-1). IUPAC PHOTOCHEMICAL GLOSSARY (1992). See also outer-sphere electron transfer.

See also:
intramolecular forces definition
Insertion reaction definition
interface seal zone definition
inositols definition
ion permeation definition
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