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general acid catalysis definition

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The catalysis of a chemical reaction by a series of Brønsted acids (which may include the solvated hydrogen ion) so that the rate of the catalysed part of the reaction is given by kHA[HA] multiplied by some function of substrate concentrations. (The acids HA are unchanged by the overall reaction.) General catalysis by acids can be experimentally distinguished from specific catalysis by hydrogen cations (hydrons) by observation of the rate of reaction as a function of buffer concentration. See also catalysis, catalytic coefficient, intramolecular catalysis, pseudo-catalysis, specific catalysis.


See also:

geminate pair definition
Hapten definition
Hansch constant definition
haloforms definition
glob-top definition