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energy of activation (Arrhenius energy of activation; activation energy), Ea (SI unit: kJ mol-1) def

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An operationally defined quantity expressing the dependence of a rate constant on temperature according to

Ea = RT2( ln k /T)pas derived from the "Arrhenius equation", k = A exp(-Ea/RT), where A (SI unit: as for the corresponding rate constant) is termed the "pre-exponential factor". See also enthalpy of activation.


See also:

element effect definition
encounter-controlled rate definition
Enzyme repression definition
eluent definition
eluent definition