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encounter complex definition

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A complex of molecular entities produced at an encounter-controlled rate, and which occurs as an intermediate in a reaction mechanism. When the complex is formed from two molecular entities it is called an "encounter pair". A distinction between encounter pairs and (larger) encounter complexes may be relevant in some cases, e.g. for mechanisms involving pre-association.


See also:

electropolish (EP) definition
ELF-sensitive equipment definition
ene reaction definition
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EMG definition