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eighteen-electron rule definition

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An electron-counting rule to which an overwhelming majority of stable diamagnetic transition metal complexes adhere. The number of nonbonded electrons at the metal plus the number of electrons in the metal-ligand bonds should be 18. The 18 electron rule in transition metal chemistry is a full analogue of the "Lewis octet rule".


See also:

Electron Deficient Compounds definition
electron density definition
electromeric effect definition
electroneutrality principle definition
Electrolyte definition