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critical micelle concentration (cmc) definition

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There is a relatively small range of concentrations separating the limit below which virtually no micelles are detected and the limit above which virtually all additional surfactant molecules form micelles. Many properties of surfactant solutions, if plotted against the concentration, appear to change at a different rate above and below this range. By extrapolating the loci of such a property above and below this range until they intersect, a value may be obtained known as the critical micellization concentration (critical micelle concentration), symbol cM, abbreviation cmc (or c.m.c.). As values obtained using different properties are not quite identical, the method by which the cmc is determined should be clearly stated. See IUPAC MANUAL APPENDIX II (1972). See also inverted micelle.


See also:

coordinate system origin definition
crossbow definition
CPMAS NMR definition
Corrin definition
Crown Conformation definition