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cage definition

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An aggregate of molecules, generally in the condensed phase, that surrounds the fragments formed, for example, by thermal or photochemical dissociation. Because the cage hinders the separation of the fragments by diffusion, they may preferentially react with one another ("cage effect") but not necessarily to re-form the precursor species. For example,

R-N=N-R, heat [R. + N2 + R.]cage R-R + N2See also geminate recombination.


See also:

buffer definition
BTAB definition
calendar cycle time definition
buried layer definition
brightfield illumination definition